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Dual-Mode Functionality in Analog-Weight-Tunable TiOx -Based RRAM: Exploiting Optical and Electrical Stimuli for Synaptic Behaviorsopen access

Authors
Park, HyogeunSo, HyojinKo, MinsuKim, SungjunKim, Sungjoon
Issue Date
Aug-2025
Publisher
American Chemical Society
Keywords
resistive switching; TiO x -based RRAM; neuromorphic synaptic emulation; photonic-electricalsynaptic function; reservoir computing
Citation
ACS Applied Electronic Materials, v.7, no.15, pp 7432 - 7445
Pages
14
Indexed
SCIE
SCOPUS
Journal Title
ACS Applied Electronic Materials
Volume
7
Number
15
Start Page
7432
End Page
7445
URI
https://scholarworks.dongguk.edu/handle/sw.dongguk/58944
DOI
10.1021/acsaelm.5c01301
ISSN
2637-6113
2637-6113
Abstract
In this study, an RRAM with a crossbar array structure incorporating an oxygen-deficient TiO y layer on top of an oxygen-rich TiO x and Al2O3 tunnel barrier was developed. The Ti top electrode underwent oxidation reactions with the oxygen-rich TiO x (x = 1.78) layer, resulting in the formation of an oxygen-deficient TiO y layer. The TiO y /TiO x structure performed functions of switching and an oxygen reservoir, enhancing switching stability and inducing analog weight modulation effects, which further reduced the current level. The oxygen ion drift and diffusion effect of the proposed device led to conductance relaxation, which also means short-term memory (STM) properties. It demonstrated stable uniformity and endurance during DC sweep measurements, and the successful implementation of multilevel characteristics was achieved by using the time-dependent weight expression of the proposed device. Reservoir computing functions were executed through pulse measurements, enabling the realization of an MNIST pattern recognition system. Additionally, synaptic functionalities were emulated, successfully demonstrating the potential for neuromorphic computing system implementation. We also demonstrated dual-mode operation by simultaneously utilizing both electrical and optical stimulation, with optical stimulation emulating synaptic function.
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