Development of an analytical method to determine methyl alcohol and isopropyl alcohol in food using static headspace gas chromatography
Development of an analytical method to determine methyl alcohol and isopropyl alcohol in food using static headspace gas chromatography
  • Lim, Heung Youl
  • Ka, Mi-Hyun
  • Chang, Nae In
  • Kim, Yong Yeon
  • Shin, Han-Seung
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초록

A method to determine methanol (MeOH) and isopropyl alcohol (IPA) was developed using static headspace sampling (HSS) with gas chromatography (GC) and gas chromatography/mass spectrometry (GC/MS). The optimized HSS-GC and HSS-GC/MS methods were validated according to the parameters. The limit of quantification (LOQ) values for MeOH analyzed by HSS-GC/MS and HSS-GC were 0.50-0.56 and 1.97 mg/L, and the corresponding values for IPA were 0.14-0.21 and 1.51 mg/L, respectively. Recoveries were determined by spiking sample matrices, such as vinegar and tea. MeOH and IPA showed excellent recoveries of 93.80-107.60% and 93.92-104.32% with corresponding precisions of 0.51-7.38% and 0.90-7.70%, respectively. Compared to solid-phase microextraction-GC/MS and HSS-GC, the HSS-GC/MS method showed outstanding values for limit of detection and LOQ with improved precision and accuracy. This HSS-GC/MS method was successfully used to monitor residual solvents in 100 food and functional food products.

키워드

FoodHeadspaceIsopropyl alcoholMethanolResidual solventRESIDUAL SOLVENTS
제목
Development of an analytical method to determine methyl alcohol and isopropyl alcohol in food using static headspace gas chromatography
제목 (타언어)
Development of an analytical method to determine methyl alcohol and isopropyl alcohol in food using static headspace gas chromatography
저자
Lim, Heung YoulKa, Mi-HyunChang, Nae InKim, Yong YeonShin, Han-Seung
DOI
10.1007/s10068-023-01356-4
발행일
2024-01
유형
Article
저널명
Food Science and Biotechnology
33
2
페이지
389 ~ 397