Effects of SO2 contamination on rising CO2 drops under high pressure

Abstract

Although the flow dynamics of pure liquid drops in other liquids has been well researched, little attention has been paid to the impacts of impurities. Hence, most of research is not directly applicable to the real world. To address this gap, we conducted numerical experiments simulating the rise of pure and contaminated drops. It was selected to study liquid CO2 drops contaminated with SO2 under high pressure because such mixtures mimic potential scenarios in which drops may leak from carbon capture and storage (CCS) facilities or pipelines. First, numerical simulation experiments were performed to validate our method by comparing our results with previous research on pure drops. Second, the validated numerical approach was applied to simulations of contaminated drops to investigate how contaminants affect rising drops. The results show that the SO2 contamination caused changes in deformation, breakup phenomena, rising velocities, surrounding flow fields and drag coefficients. Most importantly, the contamination resulted in the formation of smaller "child drops''; such breakup is not observed in pure CO2 drops. The formation of child drops in turn affects the streamlines, patterns and areas of wakes behind the contaminated drops. The addition of contaminants also enhances the dissolution rate, which is affected by the contaminant concentration and by the flow dynamics of the rising drop. Our results would improve understanding the rise of impure CO2 drops, such as drops potentially leaked by future CCS operations.