Solvent-Driven Structural Modulation of Co-Ni3S2 and Impact on Electrochemical Water Splitting

Abstract

Understanding the role of synthesis parameters in tailoring catalyst morphology is crucial for enhancing performance in electrochemical water splitting. This research systematically explores how different solvent environments affect the structural evolution and morphology of cobalt-doped nickel sulfide (Co-Ni3S2) nanomaterials. By systematically modifying the solvent environment using ethylene glycol and glycerol, distinct morphologies of Co-Ni3S2 were obtained, leading to variations in their electrocatalytic water-splitting performance. The fabricated compounds were thoroughly tested for their catalytic performance in facilitating hydrogen and oxygen evolution processes. Notably, the use of ethylene glycol as a synthesis medium led to the formation of a unique interconnected petal-like structure, significantly improving electrocatalytic activity, as evidenced by low overpotentials of 190.7 mV for HER at 10 mA cm(-2) and 414 mV for OER at 30 mA cm(-2). In contrast, when glycerol was employed as the solvent, the resulting Co-Ni3S2 material displayed overpotentials of 223.8 mV and 535 mV for HER and OER, respectively. Eventually, Co-doping was found to enhance the electrocatalytic performance, as pure Ni3S2 synthesized under the same solvent conditions exhibited higher overpotentials for both HER and OER. These findings underscore the crucial role of solvent selection in tailoring the structural and functional properties of materials for high-performance electrochemical applications.