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Palladium-Catalyzed Synthesis of Pyrrolo[1,2-α]Pyrazines From N-Phenacyl Pyrrole-2-Carbonitriles and Aryl Boronic Acids
- Authors
- Park, Hyejun; Shim, Seunghwan; Jeon, Hayoung; Lee, Hwayoung; Lee, Kiho; Lee, Kyeong; Lee, Jae Kyun; Jalani, Hitesh B.; Choi, Yongseok
- Issue Date
- Nov-2024
- Publisher
- Heterocorporation
- Keywords
- aryl boronic acids; carbo-palladation; N-phenacyl pyrrole-2-carbonitriles; pd(TFA)(2); pyrrolo[1,2-alpha]pyrazines
- Citation
- Journal of Heterocyclic Chemistry, v.61, no.11, pp 1 - 9
- Pages
- 9
- Indexed
- SCIE
SCOPUS
- Journal Title
- Journal of Heterocyclic Chemistry
- Volume
- 61
- Number
- 11
- Start Page
- 1
- End Page
- 9
- ISSN
- 0022-152X
1943-5193
- Abstract
- Herein, we have developed palladium-trifluoroacetate-catalyzed carbo-palladation reaction of pyrrole-2-carbonitriles and aryl boronic acids leading to functionally diverse pyrrolo[1,2-alpha]pyrazines under thoroughly optimized reaction conditions. The reaction proceeded smoothly and allowed the diversity-oriented synthesis of pyrrolo[1,2-alpha]pyrazines with broad substrate scope with respect to pyrrole-2-carbonitriles and aryl boronic acids.
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Related Researcher
- Lee, Kyeong
- College of Pharmacy (Department of Pharmacy)