Co-N-C anchored g-C3N4 plate enhancing surface activity for efficient visible-light photocatalytic rhodamine-B elimination and CO2 conversion

Abstract

Poor light-harvesting, fast recombination of photo-induced charge carriers, and unfavorable surface adsorption remain the major issues restricting the photocatalytic activity of g-C3N4. In this study, the Co-N-C decorated g-C3N4 (Co-N-C/g-CN) plate was developed by constructing Co-N-C on the surface of g-CN plate to improve photocatalytic rhodamine-B (RhB) degradation and CO2 conversion. The as-prepared 0.5Co-N-C/g-CN plate exhibited an exceptionally high efficiency in photocatalytic RhB degradation, with a rate of 99.5 % achieved in mere 30 min. Besides, the 0.5Co-N-C/g-CN plate also demonstrated an outstanding photocatalytic CO2 conversion rate of 33.7 μmol g−1cat h−1 within 4 h, which was more than 3.4-fold that of g-CN (9.9 μmol g−1cat h−1). Experiments demonstrated that the surface-constructed Co-N-C enhanced the visible light-harvesting and the separation of photo-induced charge carriers, boosting the optical property. Moreover, the density functionalized theory (DFT) calculations verified that the Co-N-C cocatalyst optimized O2 adsorption for the generation of superoxide radicals (·O-2), accelerating the photocatalytic RhB removal. Meanwhile, the Co-N-C was advantageous for the adsorption and activation of CO2, facilitating the photocatalytic CO2 conversion. This study provides a perspective on the surface engineering of g-CN toward enhanced photocatalytic performance. © 2024 Elsevier Ltd