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Solvothermal synthesis of three-dimensional CeO2 micropillows and their photocatalytic property

Authors
Arul, Narayanasamy SabariMangalaraj, DevanesanHan, Jeong In
Issue Date
Jul-2014
Publisher
WILEY-V C H VERLAG GMBH
Keywords
CeO2 micropillows; solvothermal synthesis; surface area; photocatalysts; optical absorption
Citation
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, v.8, no.7, pp 643 - 647
Pages
5
Indexed
SCI
SCIE
SCOPUS
Journal Title
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
Volume
8
Number
7
Start Page
643
End Page
647
URI
https://scholarworks.dongguk.edu/handle/sw.dongguk/23584
DOI
10.1002/pssr.201409200
ISSN
1862-6254
1862-6270
Abstract
Three-dimensional (3D) CeO2 micropillows were synthesized by using solvothermal method. The pH of the precursor solution was adjusted to 10 by adding ammonium hydroxide. The structural, morphology and compositional characteristics of CeO2 micropillows were investigated by XRD, SEM, TEM and EDAX. XRD analysis showed the formation of CeO2 micropillows. BET analysis showed high specific surface area for the synthesized CeO2 micropillows (191 m(2) g(-1)). Optical absorption of CeO2 micropillows showed enhanced photoabsorption ability with the estimated band gap energy of 2.8 eV. The photodegradation rate of the CeO2 micropillows was found to be 87% and obeys pseudo-first-order equation. The photocatalytic results indicated that the CeO2 micropillows exhibit enhanced photocatalytic property towards azo dye acid orange 7 (AO7) under UV-Vis light illumination.(C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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