P-type doped ambipolar polymer transistors by direct charge transfer from a cationic organic dye Pyronin B ferric chloride

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초록

We report a facile way to improve organic field effect transistor (OFET) performance based on low concentration doping of diketopyrrolopyrrole-thieno[3,2-bIthiophene (DPPT-TT) solution by an organic cationic dye, Pyronin B (PyB). DPPT-TT OFETs show significantly high field effect mobilities (up to 3.5 cm(2)v(-1) s(-1)) by optimizing the doping ratio and solvent selection. The devices also exhibit better on! off ratio by suppression of n-channel characteristics. Ultraviolet photoelectron spectroscopy and UV vis absorption spectra revealed efficient p-type doping in PyB doped DPPT-TT films, which was confirmed by the Fermi level shifting toward the highest occupied molecular orbital and red shift of the absorption spectrum. (C) 2016 Elsevier B.V. All rights reserved.

키워드

Organic field effect transistorsConjugated polymerDopingCationic dyesCharge carrier mobilityFIELD-EFFECT TRANSISTORSTHIN-FILMSSEMICONDUCTORSELECTRONICSCIRCUITSTRANSPORTDOPANTDIANHYDRIDEMECHANISMSUNIPOLAR
제목
P-type doped ambipolar polymer transistors by direct charge transfer from a cationic organic dye Pyronin B ferric chloride
저자
Huseynova, GunelXu, YongYawson, Benjamin NketiaShin, Eul-YongLee, Mi JungNoh, Yong Young
DOI
10.1016/j.orgel.2016.10.012
발행일
2016-12
유형
Article
저널명
Organic Electronics
39
페이지
229 ~ 235