Quantum nanoplasmonic alchemy: transforming yttrium into an on-chip hydrogen sensor
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We present a nanoplasmonic hydrogen sensor based on a gold-yttrium-platinum plasmonic waveguide, numerically investigated using rigorous coupled wave analysis (RCWA). Upon hydrogen absorption, the yttrium layer undergoes a reversible phase transition from metallic to semiconducting, which alters its dielectric permittivity and modulates the optical response of the device. These hydrogen-induced changes lead to a pronounced plasmon resonance red-shift (Delta lambda) and enhanced differential reflectance (Delta R), providing a sensitive optical readout of hydrogen concentration (H/Y). By tuning the waveguide height, air gap, and yttrium hydride thickness, the sensor response is further optimized, demonstrating broad spectral tunability and improved detection sensitivity compared to conventional palladium-based approaches. This work highlights yttrium hydride as a novel and tunable plasmonic material, establishing its potential for practical, real-time hydrogen detection in energy storage systems, industrial safety monitoring, and environmental applications.

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Quantum nanoplasmonic alchemy: transforming yttrium into an on-chip hydrogen sensor
저자
Subramanian, T. Senthil SivaSingh, Aditya NarayanNam, Kyung-WanKrishnappa, Manjunath
DOI
10.1039/d5cp01344e
발행일
2025-11
유형
Article
저널명
Physical Chemistry Chemical Physics
27
44
페이지
23880 ~ 23888