Annealing-Regulated Co3(PO4)2 for Enhanced Electrochemical Kinetics in Asymmetric Supercapacitors

초록

Thermal regulation of electrode materials offers an effective strategy for optimizing electrochemical kinetics in phosphate-based energy-storage systems. In this work, cobalt phosphate (Co3(PO4)2) (CoP) electrodes were directly synthesized on nickel foam through a hydrothermal route and subsequently annealed at different temperatures (300, 400, and 500 degrees C) to investigate the influence of thermal treatment on structural evolution and supercapacitive behavior. X-ray diffraction confirmed the formation of crystalline CoP, while FESEM analysis revealed a strong dependence of morphology on annealing temperature, with CoP-400 exhibiting a well-developed interconnected plate-like architecture favorable for ion transport. XPS and elemental mapping verified the successful incorporation and uniform distribution of Co, P, and O species. Electrochemical investigations demonstrated that annealing temperature critically governs charge-storage behavior, ion diffusion, and mass transport properties. Among all electrodes, CoP-400 exhibited the best electrochemical performance, delivering a high areal capacitance of 28.62 F/cm2 at 20 mA/cm2, together with the highest ionic diffusion coefficient, lowest equivalent series resistance (0.39 Omega), and dominant diffusion-controlled charge-storage contribution (89%). Furthermore, CoP-400 retained 84.44% capacitance after 12,000 cycles. An asymmetric supercapacitor assembled using CoP-400//AC achieved an areal capacitance of 302 mF/cm2, an energy density (ED) of 0.094 mWh/cm2, and excellent cycling stability. These findings highlight annealing-engineered CoP as a promising electrode material for high-performance asymmetric supercapacitors.

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