ScholarWorks@동국대학교

초록

Understanding the complex structural and chemical factors that influence ionic conduction mechanisms is paramount for developing advanced inorganic superionic conductors in all-solid-state batteries, particularly halide solid electrolytes with excellent electrochemical oxidative stability and mechanical sinterability. Herein, contrasting ionic conduction behaviors in I- and Br- substituted Li2ZrCl6 are revealed by combining experimental structural analyses and theoretical calculations. The inter-slab distance along the c-axis, which varies with the anion substitution and M2-M3 site disorder, is a key factor for opening the ab-plane conduction and facilitating the overall Li+ conduction. Increased M3 site occupancy generally leads to contracted inter-slab distance. The substantial increase in Li+ conductivity upon I substitution (from 0.40 to 0.91 mS cm-1) originates from a sufficiently expanded lattice volume owing to its large ionic radii (I- = 2.20 & Aring;), particularly inter-slab distance that facilitates the ab intra-plane Li+ conduction, which also benefits from decreased M2-M3 disorder. In contrast, Br (Br- = 1.96 & Aring;) substitution results in insufficiently expanded Li+ channels, which, exacerbated by increased M2-M3 disorder, leads to degradation in Li+ conductivity. Implementing I- substituted Li2ZrCl6 resulted in superior electrochemical performance in LiCoO2||Li-In cells compared to those with an unsubstituted catholyte.

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