ScholarWorks@동국대학교

초록

Electrocatalytic water splitting is a very promising and sustainable approach for generating hydrogen as a clean carbon-free fuel. To develop an efficient electrocatalyst for water splitting, the overpotential for this reaction must be minimized by using a capable electrocatalyst that can support the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). In this study, we prepared a unique core-shell structure, Co-metal-organic framework (MOF) derived cobalt diselenide laminated with molybdenum diselenide (MOF-CoSe2@MoSe2) and assessed its performance as a bifunctional electrocatalyst for the HER and OER in alkaline media. The CC/MOF-CoSe2@MoSe2 core-shell structure fabricated directly on a flexible carbon cloth substrate demonstrated low overpotentials (eta 10) of 109.87 and 183.81 mV for the HER and OER, respectively, and a low voltage of 1.53 V for overall water splitting activity with an electrolyzer cell with symmetric CC/MOF-CoSe2@MoSe2 electrodes. The developed CC/MOF-CoSe2@MoSe2 catalyst had excellent stability over 24 h for OER, HER, and overall water splitting activity. These results suggest that lamination of MOF with a transition metal dichalcogenide is an effective route for developing the highly efficient and sustainable bifunctional electrocatalyst for overall water splitting activity.

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