MXene (Ti3C2Tx) modified α-Co(OH)2 battery-type cathode and highly capacitive binder-free Ti3C2Tx anode for high-performance electrochemical hybrid capacitor

초록

The layered nanostructure of cobalt hydroxide has received great attention in the field of the electrochemical hybrid capacitor (EHC). However, the poor electrical conductivity and cyclic stability hinder its practical applicability. Surface modification of electrodes is considered one of the effective strategies to improve these properties. In this work, the surface of alpha-Co(OH)(2) is modified via Ti3C2T (x) MXene using a simple drop-casting method with different mass loadings and corresponding electrochemical performance is evaluated. The alpha-Co(OH)(2) surface modified with 0.05 mg cm(-2) Ti3C2T (x) MXene (CM0.05) shows the maximum specific capacity of 403 C g(-1) at the current density of 3 A g(-1). The aqueous EHC fabricated with CM0.05 as a positive electrode and two-dimensional (2D) Ti3C2T (x) MXene nanosheets as a negative electrode outperforms the EHC fabricated with the activated carbon as a negative electrode. The CM0.05//MXene EHC shows the maximum energy density of 44.5 Wh kg(-1) at the power density of 2762 W kg(-1). This also shows appreciable stability of 72% even after 5000 cycles. The flexible EHC fabricated using polyvinyl alcohol: KOH gel electrolyte demonstrates a superior energy density of 1.17 mWh cm(-2) at the power density of 11.9 mW cm(-2) with a wide operating potential of 1.6 V. Therefore, MXene (Ti3C2T (x) ) modified alpha-Co(OH)(2) can be considered as a promising electrode material for flexible EHCs.

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