Disposable electrochemical sensors based on reduced graphene oxide/polyaniline/poly(alizarin red S)-modified integrated carbon electrodes for the detection of ciprofloxacin in milk
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초록

An electrochemical sensor based on an electroactive nanocomposite was designed for the first time consisting of electrochemically reduced graphene oxide (ERGO), polyaniline (PANI), and poly(alizarin red S) (PARS) for ciprofloxacin (CIPF) detection. The ERGO/PANI/PARS-modified screen-printed carbon electrode (SPCE) was constructed through a three-step electrochemical protocol and characterized using FTIR, UV–visible spectroscopy, FESEM, CV, LSV, and EIS. The new electrochemical CIPF sensor demonstrated a low detection limit of 0.0021 μM, a broad linear range of 0.01 to 69.8 μM, a high sensitivity of 5.09 μA/μM/cm2, and reasonable selectivity and reproducibility. Moreover, the ERGO/PANI/PARS/SPCE was successfully utilized to determine CIPF in milk with good recoveries and relative standard deviation (< 5%), which were close to those with HPLC analysis. Graphical Abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature 2024.

키워드

CiprofloxacinElectrochemical sensorElectrochemically reduced graphene oxideLinear scan voltammetryPoly(alizarin red S)PolyanilineSCREEN-PRINTED ELECTRODESSENSITIVE DETERMINATIONOXIDE-POLYANILINECOMPOSITE FILMBISPHENOL-ANANOCOMPOSITECATECHOLRESIDUESALIZARINACID
제목
Disposable electrochemical sensors based on reduced graphene oxide/polyaniline/poly(alizarin red S)-modified integrated carbon electrodes for the detection of ciprofloxacin in milk
저자
Elancheziyan, MariLee, SooyeonYoon, Tae HyunSingh, ManishaLee, DogyeongWon, Keehoon
DOI
10.1007/s00604-024-06578-9
발행일
2024-09
유형
Article
저널명
Mikrochimica Acta
191
9