Multifunctional ferroelectric synaptic memristors based on HfAlOx with enhanced Pavlovian learning and physical reservoir computing systems
  • An, Gwangmin
  • Lee, Seungjun
  • Seo, Yeongkyo
  • Kim, Sungjun
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초록

With the growing demand for energy-efficient, high-speed data processing systems, ferroelectric memristors based on HfAlOx (HAO) have emerged as promising candidates for neuromorphic computing. In this study, we fabricated a metal-ferroelectric-insulator-semiconductor structure with a W/HAO/ZrO2/n+ Si stack and investigated the influence of annealing duration at relatively low-temperature (500 degrees C) on ferroelectric and synaptic properties. Grazing incidence X-ray diffraction and positive-up-negative-down measurements revealed that a 60 second annealing process maximized the orthorhombic phase content and polarization characteristics. Electrical measurements showed enhanced tunneling electroresistance and memory window for a 60-second annealed device, while polarization reversal analysis confirmed the trade-off between the dead layer thickness and ferroelectricity. The 60-second annealed device also demonstrated superior read margin and synaptic behaviors, including potentiation/depression, spike based plasticity, and Pavlovian associative learning. Finally, a 4-bit reservoir computing system was successfully implemented, achieving 98.51% MNIST pattern recognition accuracy. These results highlight the potential of HAO-based ferroelectric memristors as low-power synaptic elements for future neuromorphic hardware.

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제목
Multifunctional ferroelectric synaptic memristors based on HfAlOx with enhanced Pavlovian learning and physical reservoir computing systems
저자
An, GwangminLee, SeungjunSeo, YeongkyoKim, Sungjun
DOI
10.1039/d5cp03132j
발행일
2025-11
유형
Article
저널명
Physical Chemistry Chemical Physics
27
45
페이지
24522 ~ 24533