Self-assembled two-dimensional copper oxide nanosheet bundles as an efficient oxygen evolution reaction (OER) electrocatalyst for water splitting applications

초록

A high activity of a two-dimensional (2D) copper oxide (CuO) electrocatalyst for the oxygen evolution reaction (OER) is presented. The CuO electrode self-assembles on a stainless steel substrate via chemical bath deposition at 80 degrees C in a mixed solution of CuSO4 and NH4OH, followed by air annealing treatment, and shows a 2D nanosheet bundle-type morphology. The OER performance is studied in a 1 M KOH solution. The OER starts to occur at about 1.48 V versus the RHE (eta = 250 mV) with a Tafel slope of 59 mV dec(-1) in a 1 M KOH solution. The overpotential (h) of 350 mV at 10 mA cm(-2) is among the lowest compared with other copper-basedmaterials. The catalyst can deliver a stable current density of > 10 mA cm(-2) for more than 10 hours. This superior OER activity is due to its adequately exposed OER favorable 2D morphology and the optimized electronic properties resulting from the thermal treatment.

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