Fabrication of NiCo2S4 accumulated on metal organic framework nanostructured with multiwalled carbon nanotubes composite material for supercapacitor application

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초록

Sonication-supported hydrothermal process was used to synthesize nanoporous carbon composites of NiCo2S4@N-MWCNT and NiCo2S4@N-MWCNT/MOF67 for supercapacitor applications. The structural, morphological, and electrochemical properties of the synthesized composites were improved the use of the hydrothermal process. The composite electrodes were assembled via three-electrode configuration using 6 M KOH as electrolyte solution. The NiCo2S4@N-MWCNT and NiCo2S4@N-MWCNT/MOF-67 composites showed the specific capacitance of (254 and similar to 455) F/g, respectively, at 1 A/g. Due to the incorporation of the metal organic framework nano porous structured composite, the increment of the specific capacitance was almost 1.78-fold. The electrode shows excellent capacitance retention of 98.43% and improved the cyclic stability in presence of 6 M KOH electrolyte.

키워드

Carbon nanotubes (N-MWCNT)Metal organic framework (MOF)NiCo2S4SupercapacitorCyclic stabilityCapacitance retentionNICKEL COBALT PHOSPHATEELECTRODE MATERIALSENERGY-STORAGEELECTROCHEMICAL PROPERTIESHYDROTHERMAL SYNTHESISNANOSHEET ARRAYSFIBER PAPERGRAPHENEFOAMNANOPARTICLES
제목
Fabrication of NiCo2S4 accumulated on metal organic framework nanostructured with multiwalled carbon nanotubes composite material for supercapacitor application
저자
Ramesh, SivalingamKaruppasamy, K.Vikraman, DhanasekaranYadav, H. M.Kim, Hyun-SeokSivasamy, ArumugamKim, Heung Soo
DOI
10.1016/j.ceramint.2022.05.048
발행일
2022-10
유형
Article
저널명
Ceramics International
48
19
페이지
29102 ~ 29110