Fabrication of NiCo2S4 accumulated on metal organic framework nanostructured with multiwalled carbon nanotubes composite material for supercapacitor application

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초록

Sonication-supported hydrothermal process was used to synthesize nanoporous carbon composites of NiCo2S4@N-MWCNT and NiCo2S4@N-MWCNT/MOF67 for supercapacitor applications. The structural, morphological, and electrochemical properties of the synthesized composites were improved the use of the hydrothermal process. The composite electrodes were assembled via three-electrode configuration using 6 M KOH as electrolyte solution. The NiCo2S4@N-MWCNT and NiCo2S4@N-MWCNT/MOF-67 composites showed the specific capacitance of (254 and similar to 455) F/g, respectively, at 1 A/g. Due to the incorporation of the metal organic framework nano porous structured composite, the increment of the specific capacitance was almost 1.78-fold. The electrode shows excellent capacitance retention of 98.43% and improved the cyclic stability in presence of 6 M KOH electrolyte.

키워드

Carbon nanotubes (N-MWCNT); Metal organic framework (MOF); NiCo2S4; Supercapacitor; Cyclic stability; Capacitance retention; NICKEL COBALT PHOSPHATE; ELECTRODE MATERIALS; ENERGY-STORAGE; ELECTROCHEMICAL PROPERTIES; HYDROTHERMAL SYNTHESIS; NANOSHEET ARRAYS; FIBER PAPER; GRAPHENE; FOAM; NANOPARTICLES
제목
Fabrication of NiCo2S4 accumulated on metal organic framework nanostructured with multiwalled carbon nanotubes composite material for supercapacitor application
저자
Ramesh, Sivalingam; Karuppasamy, K.; Vikraman, Dhanasekaran; Yadav, H. M.; Kim, Hyun-Seok; Sivasamy, Arumugam; Kim, Heung Soo
DOI
10.1016/j.ceramint.2022.05.048
발행일
2022-10
유형
Article
저널명
Ceramics International
권
48
호
19
페이지
29102 ~ 29110