Green chemical and hybrid enzymatic pretreatments for lignocellulosic biorefineries: Mechanism and challenges
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초록

The greener chemical and enzymatic pretreatments for lignocellulosic biomasses are portraying a crucial role owing to their recalcitrant nature. Traditional pretreatments lead to partial degradation of lignin and hemicellulose moieties from the pretreated biomass. But it still restricts the enzyme accessibility for the digestibility towards the celluloses and the interaction of lignin-enzymes, nonproductively. Moreover, incursion of certain special chemical treatments and other lignin sulfonation techniques to the enzymatic pretreatment (hybrid enzymatic pretreatment) enhances the lignin structural modification, solubilization of the hemicelluloses and both saccharification and fermentation processes (SAF). This article concentrates on recent developments in various chemical and hybrid enzymatic pretreatments on biomass materials with their mode of activities. Furthermore, the issues on strategies of the existing pretreatments towards their industrial applications are highlighted, which could lead to innovative ideas to overcome the challenges and give guideline for the researchers towards the lignocellulosic biorefineries.

키워드

Lignocellulosic biorefineriesGreener chemicalHybrid enzymatic pretreatmentsDelignificationEnzymatic accessibilityIONIC LIQUID PRETREATMENTDEEP EUTECTIC SOLVENTSBIOLOGICAL PRETREATMENTPHYSICOCHEMICAL PROPERTIESSTEAM PRETREATMENTWATER PRETREATMENTBIOFUEL PRODUCTIONSUGARCANE BAGASSELIGNINHYDROLYSIS
제목
Green chemical and hybrid enzymatic pretreatments for lignocellulosic biorefineries: Mechanism and challenges
저자
Saratale, Rijuta GaneshPonnusamy, Vinoth KumarPiechota, GrzegorzIgliński, BartłomiejShobana, S.Park, Jeong-HoonSaratale, Ganesh DattatrayaShin, Han SeungBanu, J. RajeshKumar, VinodKumar, Gopalakrishnan
DOI
10.1016/j.biortech.2023.129560
발행일
2023-11
유형
Review
저널명
Bioresource Technology
387
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1 ~ 13