Evaluation and improvement of the NH3 adsorption capacity of Engelhard titanosilicate (ETS) materials

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초록

The purpose of this study was to evaluate and improve the ammonia adsorption performance of Na/K-ETS-10 material using an ion exchange method followed by calcination process to replace its Na+/K+ ions with H+ ions. The Na/K-ETS-10 starting material and the obtained H-type ETS-10 sample were investigated by temperature-programmed desorption of NH3, NH3 breakthrough test and NH3 absorption isotherm (10-30 A degrees C). When the modification method is used, not only the H-type ETS-10 sample showed the highest NH3 adsorption capacity of 6.2 mol/kg at 10 A degrees C, but also there is an overall remarkable improvement in the NH3 breakthrough time in comparison with original one.

키워드

Microporous; Titanosilicate; ETS-10; Modification; Ammonia adsorption; NH3; ION-EXCHANGE; MOLECULAR-SIEVE; TITANIUM SILICATE; LOCAL-STRUCTURE; CRYSTALLIZATION; AMMONIA
제목
Evaluation and improvement of the NH3 adsorption capacity of Engelhard titanosilicate (ETS) materials
저자
Kim, Shin Dong; Magnone, Edoardo; Park, Jung Hoon; Ryu, Jae Yong
DOI
10.1007/s10934-017-0442-x
발행일
2018-02
유형
Article
저널명
Journal of Porous Materials
권
25
호
1
페이지
297 ~ 302