A naphthalene-based azo armed molecular framework for selective sensing of Al3+

초록

An azo armed Schiff base chemosensor was synthesized based on a naphthalene fluorophore, which transduces greenish-yellow emission by complexing with Al3+. It emits greenish-yellow fluorescence through restricted C=N isomerization, chelation-enhanced fluorescence, and the photo-induced electron transfer mechanism. The clear visible transformation of the achromatic ligand to a chromatic ligand by the 1 : 1 complexation with Al3+ is substantiated by ESI-MS spectra. H-1 NMR, C-13 NMR, and FTIR spectroscopies are used to characterize the HL. The selectivity of the HL for Al3+ in the presence of other metal ions was investigated through absorbance and fluorescence spectroscopies. The average lifetimes of HL and L-Al3+ have been evaluated using a time-resolved photoluminescence experiment to explore the sensing mechanism. The Al3+ sensing mechanism was also established by density functional theory calculations. A reversibility experiment was performed, demonstrating that Al3+ binding to HL is reversible. The pH variation on luminescence affirms that the HL can survive in physiological pH. Finally, the lower limit of detection of 5.4 x 10(-7) and a good response in a cytotoxicity and cell imaging study confirm the usability of the ligand as an indelible signature of an effective biosensor for target Al3+.

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