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Substituent modification to prevent Dexter energy transfer for stable hyperfluorescent organic light-emitting diodes

Authors
Lee, ChanheeTsuchiya, YouichiLee, Sae YounAdachi, Chihaya
Issue Date
Jan-2026
Publisher
Oxford University Press
Keywords
device stability; Dexter energy transfer; hyperfluorescence
Citation
Chemistry Letters, v.55, no.1
Indexed
SCIE
SCOPUS
Journal Title
Chemistry Letters
Volume
55
Number
1
URI
https://scholarworks.dongguk.edu/handle/sw.dongguk/63531
DOI
10.1093/chemle/upaf240
ISSN
0366-7022
1348-0715
Abstract
Hyperfluorescent (HF) organic light-emitting diodes (OLEDs) utilizing multi-resonance (MR) type thermally activated delayed fluorescence (TADF) emitters as terminal emitters (TEs) have attracted attention for their stable, efficient device performance. Nevertheless, research to improve device lifetime remains essential, with a focus on suppressing Dexter energy transfer (DXET). In this study, we developed a bulkier TE to increase the distance between the assistant dopant (Ad) and the TE within the HF system, thereby suppressing DXET. As a result, we successfully extended the device lifetime while maintaining the EQE.
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