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Synthesis and photochemistry of new chiral keto[3,3]cyclophanes

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dc.contributor.authorShin, Ho Suk-
dc.contributor.authorPark, Bong Ser-
dc.date.accessioned2025-10-15T01:30:17Z-
dc.date.available2025-10-15T01:30:17Z-
dc.date.issued2025-10-
dc.identifier.issn0253-2964-
dc.identifier.issn1229-5949-
dc.identifier.urihttps://scholarworks.dongguk.edu/handle/sw.dongguk/61719-
dc.description.abstractWe have prepared racemates of two new chiral keto[3,3]paracyclophanes and one keto[3,3]metacyclophane by irradiation of the corresponding phenacyl benzoates tethered with a phenol moiety via conformational preorganization enabled by intramolecular charge transfer complex. Their structural properties have been analyzed by X-ray crystallography. The photochemistry of the new cyclophanes has also been examined, in which the beta C-O bond cleavage is the major reaction pathway.-
dc.format.extent5-
dc.language영어-
dc.language.isoENG-
dc.publisher대한화학회-
dc.titleSynthesis and photochemistry of new chiral keto[3,3]cyclophanes-
dc.typeArticle-
dc.publisher.location대한민국-
dc.identifier.doi10.1002/bkcs.70068-
dc.identifier.scopusid2-s2.0-105018345542-
dc.identifier.wosid001583643800001-
dc.identifier.bibliographicCitationBulletin of the Korean Chemical Society, v.46, no.10, pp 1009 - 1013-
dc.citation.titleBulletin of the Korean Chemical Society-
dc.citation.volume46-
dc.citation.number10-
dc.citation.startPage1009-
dc.citation.endPage1013-
dc.type.docTypeArticle-
dc.identifier.kciidART003256088-
dc.description.isOpenAccessY-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.description.journalRegisteredClasskci-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusNATURAL-PRODUCTS-
dc.subject.keywordPlusENTROPIC CONTROL-
dc.subject.keywordPlusCYCLOPHANES-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusDESIGN-
dc.subject.keywordAuthor[3,3]paracyclophanes-
dc.subject.keywordAuthorbeta C-O bond cleavage-
dc.subject.keywordAuthorintramolecular charge transfer-
dc.subject.keywordAuthorphotochemistry-
dc.subject.keywordAuthorpreorganization-
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