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Calcium(ii)-catalyzed [2+3] annulation of enynones: a sustainable approach to 9H-pyrrolo[1,2-a]indole frameworks

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dc.contributor.authorKale, Ashok-
dc.contributor.authorRivonker, Shubham C.-
dc.contributor.authorKim, Jong-hyuk-
dc.contributor.authorHwang, Jong Yeon-
dc.contributor.authorChoi, Yongseok-
dc.contributor.authorLee, Kyeong-
dc.date.accessioned2025-07-15T02:00:09Z-
dc.date.available2025-07-15T02:00:09Z-
dc.date.issued2025-07-
dc.identifier.issn1359-7345-
dc.identifier.issn1364-548X-
dc.identifier.urihttps://scholarworks.dongguk.edu/handle/sw.dongguk/58674-
dc.description.abstractA Ca(ii)-catalyzed, atom-economic, and regioselective [2+3] annulation reaction has been developed to synthesize 9H-pyrrolo[1,2-a]indoles by using easily accessible tryptamines and enynones. This protocol exhibits broad functional group tolerance; thus, 9H-pyrrolo[1,2-a]indole frameworks with diverse substitution patterns can be synthesized. The synthetic utility of this method is further demonstrated through its effectiveness in gram-scale preparations and versatile synthetic transformations.-
dc.format.extent4-
dc.language영어-
dc.language.isoENG-
dc.publisherRoyal Society of Chemistry-
dc.titleCalcium(ii)-catalyzed [2+3] annulation of enynones: a sustainable approach to 9H-pyrrolo[1,2-a]indole frameworks-
dc.typeArticle-
dc.publisher.location영국-
dc.identifier.doi10.1039/d5cc02204e-
dc.identifier.scopusid2-s2.0-105009896052-
dc.identifier.wosid001522492900001-
dc.identifier.bibliographicCitationChemical Communications, v.61, no.62, pp 11689 - 11692-
dc.citation.titleChemical Communications-
dc.citation.volume61-
dc.citation.number62-
dc.citation.startPage11689-
dc.citation.endPage11692-
dc.type.docTypeArticle-
dc.description.isOpenAccessY-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusSTABILITY-
dc.subject.keywordPlusINDOLES-
dc.subject.keywordAuthorAlcohol-
dc.subject.keywordAuthorCalcium-
dc.subject.keywordAuthorCalcium Compounds-
dc.subject.keywordAuthorPolycyclic Aromatic Hydrocarbons-
dc.subject.keywordAuthorRegioselectivity-
dc.subject.keywordAuthorSynthesis (chemical)-
dc.subject.keywordAuthorAnnulation Reactions-
dc.subject.keywordAuthorAtom Economic-
dc.subject.keywordAuthorFunctionals-
dc.subject.keywordAuthorGram Scale-
dc.subject.keywordAuthorRegio-selective-
dc.subject.keywordAuthorSubstitution Patterns-
dc.subject.keywordAuthorSynthesised-
dc.subject.keywordAuthorSynthetic Transformations-
dc.subject.keywordAuthorSynthetic Utility-
dc.subject.keywordAuthorTryptamines-
dc.subject.keywordAuthorCatalysis-
dc.subject.keywordAuthor9h Pyrrolo[1,2 A]indole-
dc.subject.keywordAuthorAlcohol-
dc.subject.keywordAuthorCalcium-
dc.subject.keywordAuthorChemical Compound-
dc.subject.keywordAuthorEnynone-
dc.subject.keywordAuthorKetone-
dc.subject.keywordAuthorUnclassified Drug-
dc.subject.keywordAuthorTryptamine Derivative-
dc.subject.keywordAuthorAntineoplastic Activity-
dc.subject.keywordAuthorArticle-
dc.subject.keywordAuthorCatalysis-
dc.subject.keywordAuthorChemical Analysis-
dc.subject.keywordAuthorDrug Toxicity-
dc.subject.keywordAuthorEconomic Aspect-
dc.subject.keywordAuthorNonhuman-
dc.subject.keywordAuthorNuclear Magnetic Resonance-
dc.subject.keywordAuthorSynthetic Biology-
dc.subject.keywordAuthorX Ray Crystallography-
dc.subject.keywordAuthorAnnulation Reaction-
dc.subject.keywordAuthorArticle-
dc.subject.keywordAuthorControlled Study-
dc.subject.keywordAuthorDrug Analysis-
dc.subject.keywordAuthorDrug Development-
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