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Ring-opening metathesis polymerization of Norbornene-derived cyclic olefins using Iminomethyl-hydroxyl-ligated tungsten Complexes: Fast reaction and tunable cis/trans selectivity
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Nayab, Saira | - |
| dc.contributor.author | Lee, Hyosun | - |
| dc.contributor.author | Lee, Sang-Ho | - |
| dc.date.accessioned | 2025-03-05T01:43:18Z | - |
| dc.date.available | 2025-03-05T01:43:18Z | - |
| dc.date.issued | 2025-01 | - |
| dc.identifier.issn | 1387-7003 | - |
| dc.identifier.issn | 1879-0259 | - |
| dc.identifier.uri | https://scholarworks.dongguk.edu/handle/sw.dongguk/57845 | - |
| dc.description.abstract | Highly active tungsten complexes supported by (Z)-1-(((2-hydroxyphenyl)imino)methyl)naphthalen-2-ol (LA) and (Z)-4-chloro-2-(((2-hydroxyphenyl)imino)methyl)phenol (LB) were synthesized and characterized. The ring- opening metathesis polymerization activities were assessed using i Bu 3 Al as the co-initiator at room temperature. A 100% conversion of norbornene to high-molecular-weight polynorbornene (PNB) was obtained within 10 min with tunable cis/trans selectivity of resultant polymer depending on the ligand architecture. | - |
| dc.format.extent | 4 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | ELSEVIER | - |
| dc.title | Ring-opening metathesis polymerization of Norbornene-derived cyclic olefins using Iminomethyl-hydroxyl-ligated tungsten Complexes: Fast reaction and tunable cis/trans selectivity | - |
| dc.type | Article | - |
| dc.publisher.location | 네델란드 | - |
| dc.identifier.doi | 10.1016/j.inoche.2024.113580 | - |
| dc.identifier.scopusid | 2-s2.0-85209542403 | - |
| dc.identifier.wosid | 001363532500001 | - |
| dc.identifier.bibliographicCitation | Inorganic Chemistry Communications, v.171, pp 1 - 4 | - |
| dc.citation.title | Inorganic Chemistry Communications | - |
| dc.citation.volume | 171 | - |
| dc.citation.startPage | 1 | - |
| dc.citation.endPage | 4 | - |
| dc.type.docType | Article | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
| dc.subject.keywordPlus | IMIDO ALKYLIDENE | - |
| dc.subject.keywordPlus | ROMP | - |
| dc.subject.keywordPlus | MOLYBDENUM | - |
| dc.subject.keywordPlus | CATALYST | - |
| dc.subject.keywordPlus | POLYMERS | - |
| dc.subject.keywordPlus | BEHAVIOR | - |
| dc.subject.keywordPlus | MO | - |
| dc.subject.keywordAuthor | Tungsten complexes | - |
| dc.subject.keywordAuthor | X-ray structures | - |
| dc.subject.keywordAuthor | Cyclic olefin | - |
| dc.subject.keywordAuthor | Polynorbornene | - |
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Related Researcher
- Lee, Sang Ho
- College of Engineering (Department of Chemical and Biochemical Engineering)