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Solvent assisted photochemical formation of a new keto[3,3]paracyclophaneopen access
- Authors
- Shin, Ho Suk; Moon, Da Yoon; An, Sejin; Park, Bong Ser
- Issue Date
- Jun-2022
- Publisher
- Royal Society of Chemistry
- Keywords
- Benzoic Acid; Phenols; Electron Transfer; Paracyclophane; Phenol Moiety; Photochemicals; Protic Solvents; [carbonyl; Photolysis
- Citation
- Organic & Biomolecular Chemistry, v.20, no.21, pp 4303 - 4308
- Pages
- 6
- Indexed
- SCIE
SCOPUS
- Journal Title
- Organic & Biomolecular Chemistry
- Volume
- 20
- Number
- 21
- Start Page
- 4303
- End Page
- 4308
- ISSN
- 1477-0520
1477-0539
- Abstract
- Photolysis of a phenacyl benzoate tethered with a phenol leads to a very efficient release of benzoic acid, which is suggested to occur by electron transfer and/or proton transfer from the remote phenol moiety to the triplet excited carbonyl. Photolysis of the compound in protic solvents forms a new keto[3,3]paracyclophane.
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