Detailed Information
Cited 5 time in 
Cited 5 time in 
Cited 5 time in
Metadata Downloads
Temperature dependent product distribution in photolysis of o-alkylphenacyl benzoates
- Authors
- Jang, Mi; Lim, Bum Hee; Ryu, Hyuk Jun; Park, Bong Ser
- Issue Date
- 25-Dec-2013
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Keywords
- Temperature effect; Photochemistry; Photoremovable protecting group; Benzocyclobutenol
- Citation
- TETRAHEDRON LETTERS, v.54, no.52, pp 7175 - 7179
- Pages
- 5
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- TETRAHEDRON LETTERS
- Volume
- 54
- Number
- 52
- Start Page
- 7175
- End Page
- 7179
- ISSN
- 0040-4039
1873-3581
- Abstract
- Temperature effect on photochemical reactions of ortho-alkylphenacyl benzoates, one of the recently developed photoremovable protecting groups (PPG), giving indanones (IN) and benzocyclobutenols (CB) was examined. As temperature was lowered, CB was formed preferentially over IN and the amount of IN increased as temperature was elevated. Arrhenius plot of In(IN/CB) versus 1/T gave a straight line from which Ea(IN)-Ea(CB) and A(IN)/A(CB) were obtained. The least sterically hindered 2-methylphenacyl benzoate (1) gave the highest Ea(IN)-Ea(CB) and A(IN)/A(CB) among the ortho-alkylphenacyl benzoates tested in this research including 2,4,6-trimethylphenacyl benzoate (2) and 2,4,6-triisopropylphenacyl benzoate (3). (C) 2013 Elsevier Ltd. All rights reserved.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Natural Science > Department of Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.