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Highly active cobalt(II) and copper(II) complexes supported by aminomethylquinoline mediating stereoselective ring-opening polymerization of rac-lactide
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Lee, Jaegyeong | - |
| dc.contributor.author | Nayab, Saira | - |
| dc.contributor.author | Kumar, Ameet | - |
| dc.contributor.author | Kim, Dongil | - |
| dc.contributor.author | Jung, Hyewon | - |
| dc.contributor.author | Lee, Sang-Ho | - |
| dc.contributor.author | Cho, Daeheum | - |
| dc.contributor.author | Lee, Hyosun | - |
| dc.date.accessioned | 2024-08-08T11:31:15Z | - |
| dc.date.available | 2024-08-08T11:31:15Z | - |
| dc.date.issued | 2024-04 | - |
| dc.identifier.issn | 0253-2964 | - |
| dc.identifier.issn | 1229-5949 | - |
| dc.identifier.uri | https://scholarworks.dongguk.edu/handle/sw.dongguk/21703 | - |
| dc.description.abstract | Cobalt(II) and copper(II) complexes supported by 4-(quinolin-2-ylmethyl)morpholine (L) were characterized, and their reactivity toward the ring-opening polymerization (ROP) of rac-lactide (rac-LA) was studied. The use of [LMCl2]/(LiOPr)-Pr-i and [LMCl2]/LiMe (M = Co, Cu) resulted in over 95% conversion within 10 min at 25 degrees C. The effect of the initiating group and geometry of the metal complexes steered the heterotactic enchainment of the resultant polylactide(PLA). The Co(II)/LiMe system represents the first example of the ROP of rac-LA with high heterotactic enchainment (P-r = 0.92) with 98% conversion at 0 degrees C. | - |
| dc.format.extent | 5 | - |
| dc.language | 영어 | - |
| dc.language.iso | ENG | - |
| dc.publisher | 대한화학회 | - |
| dc.title | Highly active cobalt(II) and copper(II) complexes supported by aminomethylquinoline mediating stereoselective ring-opening polymerization of rac-lactide | - |
| dc.type | Article | - |
| dc.publisher.location | 대한민국 | - |
| dc.identifier.doi | 10.1002/bkcs.12828 | - |
| dc.identifier.scopusid | 2-s2.0-85185695402 | - |
| dc.identifier.wosid | 001163673300001 | - |
| dc.identifier.bibliographicCitation | Bulletin of the Korean Chemical Society, v.45, no.4, pp 317 - 321 | - |
| dc.citation.title | Bulletin of the Korean Chemical Society | - |
| dc.citation.volume | 45 | - |
| dc.citation.number | 4 | - |
| dc.citation.startPage | 317 | - |
| dc.citation.endPage | 321 | - |
| dc.type.docType | Article | - |
| dc.identifier.kciid | ART003071671 | - |
| dc.description.isOpenAccess | N | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.description.journalRegisteredClass | kci | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
| dc.subject.keywordPlus | METHYL-METHACRYLATE | - |
| dc.subject.keywordPlus | STRUCTURAL-CHARACTERIZATION | - |
| dc.subject.keywordPlus | LIGANDS | - |
| dc.subject.keywordPlus | DERIVATIVES | - |
| dc.subject.keywordPlus | CU(II) | - |
| dc.subject.keywordPlus | PRECATALYSTS | - |
| dc.subject.keywordPlus | MAGNESIUM | - |
| dc.subject.keywordPlus | ZINC(II) | - |
| dc.subject.keywordPlus | ZN(II) | - |
| dc.subject.keywordAuthor | aminomethylquinoline | - |
| dc.subject.keywordAuthor | cobalt-complex | - |
| dc.subject.keywordAuthor | copper-complex | - |
| dc.subject.keywordAuthor | heterotactic PLA | - |
| dc.subject.keywordAuthor | ring-opening polymerization | - |
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Related Researcher
- Lee, Sang Ho
- College of Engineering (Department of Chemical and Biochemical Engineering)