Effect of gold nanoparticles laced anode on the bio-electro-catalytic activity and power generation ability of compost based microbial fuel cell as a coin cell sized device

Abstract

As anodic performance can control the bio-electro-catalytic activity and overall power generation ability of cheaper compost based microbial fuel cells (MFC), bio-compatible gold nanoparticles (AuNPs) laced carbon fiber electrode is used for enhancing the efficiency. Casein peptide as a reducing and capping agent is used to synthesize bio-functional cubic AuNPs with absorption wavelength of 530 nm. The results of Cyclic Voltammetry (C-V) and electrochemical impedance spectroscopy shows that AuNPs laced electrode exhibited increased current density and better bio-electro-catalytic activity than the bare electrode which shows selective response with respect to type of compost and fuel concentration in a coin cell sized MFC. Current-Voltage (I-V) measurements show that due to the increase in the bio-electro-catalytic activity, the electrical power increases from 1.6 mW per m2 to 18.34 mW per m2 at room temperature in case of carbon rich compost at an optimized fuel concentration of 0.2 g per ml. The temperature dependence bipolar C-V measurements shows the enhancement in bio-electrocatalytic activity with increase in temperature. Also, significant improvement in durability and stability of MFC was observed with the lacing of AuNPs.