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New RNA Purine Building Blocks, 4-Selenopurine Nucleosides: First Synthesis and Unusual Mixture of Sugar Puckerings
- Authors
- Yu, Jinha; Kim, Jin-Hee; Lee, Hyuk Woo; Alexander, Varughese; Ahn, Hee-Chul; Choi, Won Jun; Choi, Jungwon; Jeong, Lak Shin
- Issue Date
- Apr-2013
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- nucleic acids; nucleosides; RNA; selenonucleosides; X-ray crystallography
- Citation
- CHEMISTRY-A EUROPEAN JOURNAL, v.19, no.18, pp 5528 - 5532
- Pages
- 5
- Indexed
- SCI
SCIE
SCOPUS
- Journal Title
- CHEMISTRY-A EUROPEAN JOURNAL
- Volume
- 19
- Number
- 18
- Start Page
- 5528
- End Page
- 5532
- ISSN
- 0947-6539
1521-3765
- Abstract
- Writer's blocks: The first synthesis of RNA purine building blocks, 4'-selenoadenosine and 4'-selenoguanosine was achieved from D-ribose by regioisomeric rearrangement, which was confirmed by X-ray crystallography. 4'-Selenoadenosine exists in an unusual mixture of north and south conformers in the solid state. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Related Researcher
- Ahn, Hee Chul
- College of Pharmacy (Department of Pharmacy)